The consent submitted will only be used for data processing originating from this website. Slurries consequently give the same advantageous The British PE4 consists of 88.0% RDX, 1.0% pentaerythrite dioleate and 11.0% DG-29 lithium grease (corresp. HBX was developed during WWII that replaced the more shock-sensitive TORPEX used in depth bombs and torpedoes. [8] Although other PBXs have since been successfully formulated for a wide range of applications, only a handful have displayed the combination of adequate energy content, mechanical properties, sensitivity, and chemical stability required for stockpile nuclear weapons. This is the first new explosive production by Royal Ordnance North America (RONA) as the operating contractor at Holston. The plasticized form of RDX, composition C-4, contains 91% RDX, 2.1% polyisobutylene, 1.6% motor oil, [30] Both patent claims were initiated in Austria; and described the manufacture of RDX by nitrating hexamethylenetetramine. US Army Ordnance held the same viewpoint and wanted to continue using TNT. [22] If ingested, patients may be administered a dose of active charcoal to adsorb some of the toxins, and haloperidol intramuscularly and diazepam intravenously to help the patient control seizures until it has passed. The warhead for the 2.75-inch "Mighty Mouse" rocket was filled with HBX (40 percent RDX, 38 percent TNT, 17 percent aluminum powder, and 5 percent desensitizers) or composition B (59 percent RDX, 40 percent TNT is typically 25-33% of the mixture with 1% wax as a binder. COMMON EXPLOSIVES RDX A4 HMX A5 DATB . [37][39] The ROF Bridgwater plant brought in ammonia and methanol as raw materials: the methanol was converted to formaldehyde and some of the ammonia converted to nitric acid, which was concentrated for RDX production. Included are the results of various explosive performance tests, such as detonation pressure, cylinder expansion (cylex),and wedge tests, as well as additional material sensitivity studies (large-scale gap test and small-scale gap test). An exposure level was determined and a one thousand fold safety factor was used to lower the Army exposure level to 0.15 mg/m^3. The result was the Wabash River Ordnance Works run by E. I. du Pont de Nemours & Company. PE4 is a conventional plastic explosive, widely used for the production of improved energetic systems for defensive and offensive use. Introduction. Finally, Table 6 shows the test results of the following composition: mechanical mixture of por-Si (45%) and red lead (55%). [21], RDX is classified by chemists as a hexahydro-1,3,5-triazine derivative. The standard proportions of ingredients (by weight) are 59.5% RDX (detonation velocity of 8,750m/s) and 39.5% TNT (detonation velocity of 6,900m/s), phlegmatized with 1% paraffin wax. It is non-hygroscopic and possesses satisfactory stowage properties. [27], During World War II, Germany used the code names W Salt, SH Salt, K-method, the E-method, and the KA-method. It detonates only with a detonator, being unaffected even by small arms fire. [8] The first public reference in the United Kingdom to the name RDX, or R.D.X., to use the official title, appeared in 1948; its authors were the managing chemist, ROF Bridgwater, the chemical research and development department, Woolwich, and the director of Royal Ordnance Factories, Explosives; again, it was referred to as simply RDX.[9]. [61][62], Ahmed Ressam, the al-Qaeda Millennium Bomber, used a small quantity of RDX as one of the components in the bomb that he prepared to detonate in Los Angeles International Airport on New Year's Eve 19992000; the bomb could have produced a blast forty times greater than that of a devastating car bomb. The symptom complex involved nausea, vomiting, generalized seizures, and prolonged postictal confusion and amnesia; which indicated toxic encephalopathy. When the U.S. entered the war, Amatol was adopted for loading high explosive shells. The newer PE7 consists of 88.0% RDX, 1.0% DMDNB taggant and 11.0% of a binder composed of low molecular mass hydroxyl-terminated polybutadiene, along with an antioxidant and an agent preventing hardening of the binder upon prolonged storage. Introduction 1.1 Scope 1.2 Approvals - Authorization of the explosives 1.3 Regulation of use 1.4 Required documentation 1.5 Continuing authorization 2. Drying with forced air for 16 hours at 50C to 60C is recommended to eliminate excess moisture. It is less sensitive than pentaerythritol tetranitrate (PETN). Composition of Emulsion Explosives. The finer they are the better they help to absorb and suppress shock. High-velocity gelatin is particularly useful as a seismic explosive, and is also used in deep well and underwater work. if(typeof ez_ad_units != 'undefined'){ez_ad_units.push([[250,250],'globalsecurity_org-banner-1','ezslot_6',135,'0','0'])};__ez_fad_position('div-gpt-ad-globalsecurity_org-banner-1-0'); On 30 August 1999 Holston Army Ammunition Plant restarted production of new explosives to fill an order for Composition CXM-3. Since it has existed for such a short time, researchers conclude that they simply have yet to find its most dense crystalline form. 3. [50], The United Kingdom's intention in World War II was to use "desensitised" RDX. The specific explosive, Composition C, was 88.3% RDX and 11.7% non-oily, non-explosive plasticizer. "Reclamation of RDX from C-4 Explosives" by the Jolly Roger, American Ordnance M112 Demolition Block datasheet, American Ordnance M183 Demolition Charge datasheet, Ensign-Bickford M112 Demolition Block datasheet, Accurate Energetic Systems M112 Demolition Block datasheet, https://en.wikipedia.org/w/index.php?title=C-4_(explosive)&oldid=1158107329, Max heat of detonation with liquid water, kilocalories per gram, Max heat of detonation with gaseous water, kilocalories per gram, Remains plastic with no exudation, Celsius, This page was last edited on 2 June 2023, at 01:09. They were the Western Cartridge Company, E. I. du Pont de Nemours & Company, and Tennessee Eastman Company, part of Eastman Kodak. This explosive is a mechanical mixture of Ammonium Nitrate and TNT. It is often processed above its self-heating temperature, yet it is safely processed in 300-gallon melt kettles. [7][8][9] Depending on its intended usage and on the manufacturer, there are differences in the composition of C-4. The melting point of Composition C-3 is 68C, and it is soluble in acetone. It is most commonly manufactured in weight strengths of 20 to 60 percent. The combination will often give better overall economy than straight slurry or dry blasting agent. It is readily detonated by Mercury Fulminate and other high explosives. [34], At the beginning of the 1940s, the major US explosive manufacturers, E. I. du Pont de Nemours & Company and Hercules, had several decades of experience of manufacturing trinitrotoluene (TNT) and had no wish to experiment with new explosives. It was declared that the British had been able to handle it without incident for 2 years and that the risk was worth the advantage gained in its underwater power. Owing to shortages of TNT and RDX (cyclonite) most World War II mines had had 50/50 ammonium nitrate and TNT (amatol) warheads. Grenade Assembly consists of PBXN-5 explosive booster pellet, PBXN-9 explosive pellets, grenade tube, and male and female grenade shells. RDX was used in one of the first plastic explosives. [51] Nonetheless, by May 1942 Wellington bombers began to deploy depth charges containing Torpex, a mixture of RDX, TNT, and aluminium, which had up to 50 percent more destructive power than TNT-filled depth charges. [28], Among field troops in Vietnam it became common knowledge that ingestion of a small amount of C-4 would produce a "high" similar to that of ethanol. [citation needed], It starts to decompose at approximately 170C and melts at 204C. @media only screen and (min-device-width : 320px) and (max-device-width : 480px) { They suspect these ill-defined RDX crystallites present at cook-off temperatures were the source of the reaction violence at cook-off. [24], RDX was reported in 1898 by Georg Friedrich Henning, who obtained a German patent (patent No. [29][30] The British patent claims included the manufacture of RDX by nitration, its use with or without other explosives, its use as a bursting charge and as an initiator. Composition A-3 is appreciably more brisant and powerful than TNT; its velocity of detonation is approximately 27,000 fps. .mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}. In another application of slurry boosting, the slurry is placed in a position where fragmentation is difficult, such as a hard toe or a zone of hard rock in the burden. These were not the only laboratories to work on RDX, Gilman's 1953 account of the RossSchiessler method was based on unpublished work from laboratories at the Universities of Michigan, Pennsylvania, Cornell, Harvard, Vanderbilt, McGill (Canada), Bristol (UK), Sheffield (UK), Pennsylvania State College, and the UK's research department. [8] However, burning C-4 produces poisonous fumes, and soldiers are warned of the dangers of personal injury when using the plastic explosive. [7], The shock sensitivity of C-4 is related to the size of the nitramine particles. The melt-cast explosive Octol is a TNT-based explosive (70% HMX:30% TNT or 75 percent HMX, 25 percent TNT). The general relationship between the SiO 2 content of magma and the amount of volatiles is shown in Figure 4.2.2. Explosive (NEW) 535 lbs. The charge assembly M183 consists of 16 block demolition charges M112, four priming assemblies and carrying case M85. Yet the new explosive, being liquid, could be poured into crevices in rocks, and was so useful as a blasting agent that its manufacture went on until a large vessel carrying cases of the explosive from Hamburg to Chili blew up at sea. Composition A is used by the military in land mines and 2.75 and 5 inch rockets. Ditching dynamite is a name given to 50 percent straight dynamite. [45] The Woolwich or direct nitration process has at least two serious disadvantages: (1) it used large amounts of nitric acid and (2) at least one-half of the formaldehyde is lost. [74], Oral toxicity of RDX depends on its physical form; in rats, the LD50 was found to be 100mg/kg for finely powdered RDX, and 300mg/kg for coarse, granular RDX. Variants have different proportions and plasticisers and include composition C-2, composition C-3, and composition C-4.[1]. [39], A different method of production to the Woolwich process was found and used in Canada, possibly at the McGill University department of chemistry. [11] The kettle is tumbled to obtain a homogeneous mixture. [83], RDX has been used as a rodenticide because of its toxicity. Slurry explosives may or may not require priming. Ammonia gelatin is commonly manufactured in weight strengths of 30 to 80 percent with corresponding cartridge strengths of 35 to 72 percent. Straight gelatin has two characteristic detonation velocities, the confined velocity and a much lower velocity which results from insufficient confinement, insufficient initiation, or high hydrostatic, pressure. 3.2.2 Tolrances physiques. It is widely used in quarrying, stripping, and in well-ventilated mines for smaller diameter holes of small blasting operations. C-4, or composition 4, is one variety of plastic explosive. A semigelatin is comparable to an ammonia gelatin as a low-density ammonia dynamite is comparable to a high-density ammonia dynamite. The velocity of detonation is approximate y 26,000 fps. [52], A Semtex bomb was used in the Pan Am Flight 103 (known also as the Lockerbie) bombing in 1988. It is used as the main explosive filling in artillery projectiles, rockets, land mines, hand grenades and various other munitions. Distinctive standard colours indicate the explosive component: C4, or PE4 ( British) is white and Semtex-H is orange. [12], C-4 is very stable and insensitive to most physical shocks. Libyan terrorists used Semtex in 1988 to down Pan Am Flight 103 over Lockerbie, Scotland, killing 270 persons. [9] RDX was produced by continually adding hexamine and concentrated nitric acid to a cooled mixture of hexamine and nitric acid in the nitrator. a For open-system degassing, the release of volatiles will decrease the buoyancy and . Thus, more energy can be loaded into a given volume of borehole. [40][47] Werner Emmanuel Bachmann, from Michigan, successfully developed the "combination process" by combining the Ross and Schiessler process used in Canada (aka the German E-method) with direct nitration. [23], If C-4 is marked with a taggant, such as DMNB, it can be detected with an explosive vapor detector before it has been detonated. TNT, and 1 percent wax). Detasheet is a plastic explosives, manufactured by DuPont containing PETN with nitrocellulose and a binder. Because of its slow, heaving action, the low-velocity series is well suited to blasting soft material such as clay- shale or where a coarse product such as riprap is desired. It is often mistaken as dynamite, perhaps fuelled by . C-4 is composed of explosives, plastic binder, plasticizer to make it malleable, and usually a marker or odorizing taggant chemical. It suffered from a relatively limited range of serviceable temperatures, and was replaced by Composition C-2 around 1943. Explosive materialsthat require detonation e.g. Composition H6 is a widely used main charge filling for underwater blast weapons such as mines, depth charges, torpedoes and mine disposal charges. In weapon applications, computational models require experimental data to determine certain specific output parameters of H6 to predict various underwater blast scenarios. This was based on reacting paraformaldehyde and ammonium nitrate in acetic anhydride. C-4 cannot be detonated by a gunshot or by dropping it onto a hard surface. The hexamine plant was supplied by Imperial Chemical Industries. AFX-757 is an extremely insensitive explosive developed by the Air Force Research Laboratory/High Explosives Research and Development Facility, Eglin AFB, Fla. [25] The German military started investigating its use in 1920, referring to it as hexogen. [55][56] It also is believed to be the explosive used in the 2010 Moscow Metro bombings. There are three fundamental types: mechanical, nuclear, and chemical. For example, the complete severing of a 36 centimetres (14in) deep I-beam takes between 680 and 910g (1.50 and 2.01lb) of C-4 when properly applied in thin sheets. A 40lb (18kg) shaped charge munition (marked to indicate a Composition B filling) used for various demolition purposes such as boring a hole for a cratering charge. Nuclear Weapons FAQ section 8.1.1: The Design of Gadget, Fat Man, and "Joe 1" (RDS-1), https://en.wikipedia.org/w/index.php?title=Composition_B&oldid=1126524682, Short description is different from Wikidata, Articles with unsourced statements from August 2009, Creative Commons Attribution-ShareAlike License 4.0, This page was last edited on 9 December 2022, at 20:41. It is used as the main explosive filling in artillery projectiles, rockets, land mines, hand grenades and various other munitions. MIL-STD-1316 EXPLOSIVES COMPOSITION A3 COMPOSITION A4 COMPOSITION A5 COMPOSITION CH6 PBX-9407 PBXN-5 PBXN-6 DIPAM HNS-I HNS-II TETRYL. CXM-3 will be supplied to Atlantic Research Corporation to fill warheads for the Tomahawk missile system. explosive, any substance or device that can be made to produce a volume of rapidly expanding gas in an extremely brief period. Ammonia dynamites (extra dynamite) are the most widely used cartridge explosives. Properties []. [82] Concerns have been raised by research published in late 2017 indicating that the issue has not been addressed correctly by U.S. [11] Additional tests were done including the "pendulum friction test", which measured a five-second explosion temperature of 263C to 290C. By April 1943, RDX was being manufactured there. Since an adequate supply of oxygen cannot be drawn from the air, asource of oxygen must be incorporated into the explosive mixture. Fire Protection Association, shall contain no ingredient that is classified as an explosive. Some of those weapons and explosives have been used by the IRA in terrorist attacks in the United Kingdom and in other European countries. It remained a service item through the Korean War, but had marginal plasticity at the very low temperatures encountered in Korean winters, and was significantly toxic, including by vapour and skin absorption. [66], In the 2019 Pulwama attack in India, 250kg of high-grade RDX was used by Jaish-e-Mohammed. Comp A-3 explosives are made from RDX and wax. Fig. The hot melt liners were developed to coat and eliminate metal-to metal pinch points. The gas exerts pressure in the form of a shock wave, which demolishes the target by cutting, breaching, or cratering. Composition A-3 is a wax-coated, granular explosive, consisting of 91% RDX and 9% desensitizing wax. [13] Detonation can be initiated only by a shockwave, such as when a detonator inserted into it is fired. It may be white or buff, depending upon the color of the wax used to coat the powdered RDX. Composition C-1 contained a slightly smaller proportion of RDX, but used an explosive plasticiser, which contained tetryl, nitrocellulose and a mixture of nitroaromatics produced during the manufacture of TNT (containing trinitrotoluene, dinitrotoluene, and mononitrotoluene), and a trace of solvent. Under normal conditions, RDX has a Figure of Insensitivity of exactly 80 (RDX defines the reference point). [9] In October 2000, the group used C-4 to attack the USS Cole, killing 17 sailors. "The Army conducted lethality testing of the PAC-3 MSE lethality enhancer titanium fragments against Composition B explosive from July 2015 through June 2016 at Aberdeen Proving Ground, Maryland . HBX is a form of high explosive made from TNT, RDX, aluminum, lecithin, and wax. Composition C-3 is 77% RDX, 3% tetryl, 4% TNT, 1% NC, 5% MNT (mononitrotoluol), and 10% DNT (dinitrotoluol). Composition B is related to Cyclotol, which has a higher proportion of RDX (up to 75%). The GBU-28 contains only six hundred pounds of Tritonal. Archived from the original (PDF) on 2015-06-15. [40] By 1942 the Royal Air Force's annual requirement was forecast to be 52,000 long tons (53,000t) of RDX, much of which came from North America (Canada and the US). [69], RDX, when exploded in air, has about 1.5 times the explosive energy of TNT per unit weight and about 2.0 times per unit volume. The binder has two important jobs: It coats the explosive material, so it's less sensitive to shock and heat. Composition: Kr45Ss55 is microcrystalline silicon with a particle size of 5 to 10 microns (45%) and red lead (55%). Display Fireworks have PE3 if: The basic idea of plastic explosives, also called plastic bonded explosives (PBX), is to combine explosive chemicals with a plastic binder material. The demolition charge M112 is a rectangular block of Composition C-4 approximately 2 inches by 1.5 inches and 11 inches long, weighing 1.25 Lbs. velocity regardless of water pressure or degree of confinement. in June 1942. It has a density 1.481.60g/ml, does not become hard even at 55C (67F), and does not exude at +77C (171F). To this end, the critical diameter dc, which is the minimum diameter which will sustain a stable detonation, and the limiting value of the velocity of detonation at infinite charge diameter D-infinity, were determined for unconfined cylinders of H6. Blasting gelatin attains a very high detonation velocity and has excellent The booster had heretofore been loaded with tetryl pellets. For a foxhole, 10 pounds of explosive will usually be sufficient. 1. The first Semtex shipment under the resumed exportswent to the British Defense Ministry. [60] Further reports on the bombs used in the 1999 apartment bombings indicated that while RDX was not a part of the main charge, each bomb contained plastic explosive used as a booster charge. There is no toxicological data for DMDNB's effects on the human body, but tests were done on laboratory animals and they showed a reversible liver hypertrophy in rats that were exposed to DMDNB. It sold hundreds of tanks, thousands of firearms and large quantities of Semtex to Iran, Iraq, Libya, Syria, Cambodia and other trouble spots, a practice that stopped long ago. Classes are measured by granulation. This mixture is wet and must be dried after transfer to drying trays. Composition C-4 (comp C4) is a commercial American plastic explosive including 1,3,5-trinitro-1,3,5-triazinane (RDX) as an energetic filler bonded by the softened matrix of polyisobutylene binder , and it has variable military applications as a destructive material . [23][21] Others would ingest C-4, commonly obtained from a Claymore mine, to induce temporary illness in the hope of being sent on sick leave.[29]. But these guns, of which one or two were used in the Spanish-American War, were very cumbersome and slow in use. A Low-Energy Exploding Foil Initiator (LEEFI) is a low-energy input device with high-energy output that can detonate a main charge of PBXN-9. [40] Given the immediate need for RDX, the US Army Ordnance, at Blandy's request, built a plant that copied the equipment and process used at Woolwich. Their weapon of choice is a pliable, odorless substance that is twice as powerful as TNT and is virtually invisible to conventional security devices. The weapon is effective against a majority of hardened targets previously vulnerable only to munitions in the 2,000 pound class. A slurry and a dry blasting agent may be used in the same borehole in "slurry boosting," with the buk of the charge being dry blasting agent. Very The velocity of detonation is about 7600m/s (25,000 feet per second. When cast, it has a specific gratity of 1.65 and a confined detonation velocity of 24,000 to 25,000 fps. [46], The vast production of RDX could not continue to rely on the use of natural beeswax to desensitize the RDX. [40], The NDRC instructed three companies to develop pilot plants. It was used widely in World War II and remains common in military applications. It is manufactured in thin flexible sheets with a rubbery texture, and is generally coloured either reddish/orange (commercial) or green (military). By mixing nitroglycerine and guncotton he found a comparatively slow-burning powder which he called ballistite, and this, when he gave it to the world in 1888, caused a very great sensation. It should be easy to detonate on demand but difficult to explode accidentally. [37], The United Kingdom and British Empire were fighting without allies against Nazi Germany until the middle of 1941 and had to be self-sufficient. The final material is a solid with a dirty white to light brown color, a putty-like texture similar to modeling clay, and a distinct smell of motor oil. Cast pentolite is used as a primer and booster for blasting agents where its high detonation pressure assures efficient initiation of the blasting agent. [10], The manufacturing process for Composition C-4 specifies that wet RDX and plastic binder are added in a stainless steel mixing kettle. smell, taste, etc.). The analytical techniques of time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy have been demonstrated to discriminate finite differences in different C-4 sources. [35], The explosive shells fired by the MK 108 cannon and the warhead of the R4M rocket, both used in Luftwaffe fighter aircraft as offensive armament, both used hexogen as their explosive base. Technical data according to the Department of the Army for the Composition C-4 follows. Semtex 10 is a Czech plastic explosive which is used for under water blasting and demolition of rocks. As with Composition B, Composition C is no longer being used as a gun projectile main charge. Chemical, morphological structural differences, and variation in atomic concentrations are detectable and definable. C-4 is a member of the Composition C family of chemical explosives. The specific gratity varies from I.i to i.6. Relative numbers and positions of RDX particles have been measured from a series of 50 fingerprints left after a single contact impression. This method of analysis is limited by manufacturing variation and methods of distribution. Soldiers were exposed to C-4 either due to inhaling the fumes, or due to ingestion, made possible by many small particles adhering to the knife having been deposited into the cooked food. [52][70], RDX is insoluble in water, with solubility 0.05975 g/L at temperature of 25C. [43] James B. Conant, chairman of Division B, wished to involve academic research into this area. Even if no taggant is used, sophisticated forensic means can still be employed to identify the presence of C-4. It can be used where an explosive with more power and brisance is of tactical advantage and there is no objection to a slight increase of sensitivity. [81] It is known to be a kidney toxin in humans and highly toxic to earthworms and plants, thus army testing ranges where RDX was used heavily may need to undergo environmental remediation. Straight dynamite has a high detonation velocity which gives a shattering action. Ammonia ("extra") dynamites have replaced straight dynamite in most applications. The term composition is used for any explosive material compounded from several ingredients. The Anti-Personnel Obstacle Breaching System (APOBS) Detonating Cord Assembly consists of PBXN-8 explosive, silicone rubber, polyamide yarn type I and II, and composition A-5 explosive. Like a high-density extra dynamite, it contains a low proportion of nitro-glycerin and a high proportion of ammonium nitrate. [35][40] The combination process required large quantities of acetic anhydride instead of nitric acid in the old British "Woolwich process". To view the purposes they believe they have legitimate interest for, or to object to this data processing use the vendor list link below. RDX was widely used during World War II, often in explosive mixtures with TNT such as Torpex, Composition B, Cyclotols, and H6. [25][26] In this patent, the medical properties of RDX were mentioned; however, three further German patents obtained by Henning in 1916 proposed its use in smokeless propellants. The material was plastic between 0 and 40 C (32-104 F), but was brittle at colder temperatures and gummy at higher temperatures. [citation needed], RDX sublimes in vacuum, which restricts or prevents its use in some applications. [20]:323 Impact tests done by the U.S. military indicate composition C-4 is less sensitive than composition C-3 and is fairly insensitive. Slurry blasting agents contain nonexplosive sensitizers or fuels such as carbon, sulfur, or aluminum, and are not cap sensitive; whereas slurry explosives contain cap- sensitive ingredients such as TNT and the mixture itself may be cap sensitive. Manage Settings Polynitrocubane Super Explosives are a family of new energetics. In reality ONC does not achieve this theoretical density. When the charge is detonated, the explosive is converted into compressed gas. Flammable materials, e.g. The test results for the EC's response time are also shown in Table 6. [7], C-4 is manufactured by combining the above ingredients with binders dissolved in a solvent. This was a low quality explosive but was later improved by the addition of about 20% aluminum to produce minol. The explosive composition PAX-3 is a high blast explosive that maintains metal pushing capability for applications. Semigelatin can be used to replace ammonia dynamite when more water resistance is needed. Although ANFO is not generally suitable for military use, since it's troublesome to store without drying out, mixtures of AN and TNT known as "amatols" were used in both WWI and WWII as a means of stretching the supply of explosives. It was standardised as Composition C when introduced to US service. twin-unit) to provide some insurance against loss of production due to fire, explosion, or air attack. Substantial quantities of the explosive have been stolen from industrial enterprises in the Czech and Slovak republics for sale on the black market. Aluminized slurries have been used in extremely hard rock with excellent results. Amatol is used as a substitute for TNT and is to be mainly found in large caliber shells. Open- and closed-system degassing feedbacks have a strong control magma ascent and eruptive style. Each priming assembly includes a five-or-twenty-foot (1.5 or 6.1m) length of detonating cord assembled with detonating cord clips and capped at each end with a booster. [9] The RDX was purified and processed for its intended use; recovery and reuse of some methanol and nitric acid also was carried out. Some of our partners may process your data as a part of their legitimate business interest without asking for consent. Baratol is a composition of barium nitrate and TNT. Straight dynamite generally has poor fume This guideline is published in accordance withPart 3 of the Explosives Regulations, 2013 (ER, 2013). In the original Woolwich process, RDX was phlegmatized with beeswax, but later paraffin wax was used, based on the work carried out at Bruceton. [1] Only 20% of the vials burned, and none exploded. [21] A strong link to central nervous dysfunction is observed. This reduced the toxicity while increasing the concentration of RDX and improving safety of use and storage. [11], Composition C-4 exists in the U.S. Army Hazardous Components Safety Data Sheet on sheet number 00077. Amatol 80/20 (used in Bangalore Torpedoes), produces white smoke on detonation, while Amatol 50/50 produces a smoke, less black than straight TNT. Its skin was much harder than that of a standard iron bomb, consisting of a single-piece, forged warhead casing of one-inch, high-grade steel. The high density of barium nitrate gives baratol a density of at least 2.5. In general, high explosives are compositions and mixtures of ingredients capable of instantaneously releasing large amounts of energy and doing work of various kinds on objects and bodies surrounding them. In 1944 the M104 auxiliary booster was first given to Redstone Arsenal as an experimental order with instructions to develop a manufacturing procedure for loading it with tetrytol. C-4 is relatively insensitive and can be detonated only by the shock wave from a detonator or blasting cap. Dynamite has been replaced by the more destructive and easily concealed Semtex. complete detonation. The loading stations were advised that they must take adequate care in mixing and loading and in the handling of the loaded items. The components of the assembly are issued in the carrying case. An example of data being processed may be a unique identifier stored in a cookie. Blasting gelatin is also known as "oil well explosive.". It was replaced by HBX or HBX-1 later in WWII. C4 has a detonation velocity of 8092m/s (26550ft/s) at high density and velocity of 7550m/s (24770ft/s) at low density 1.48g/ml. The toxicity of C-3 was reduced, the concentration of RDX was increased, giving it improved safety during usage and storage. The review showed that, at the moment, the most commonly used composition is a hexogen-based explosive bonded with a chemically cross-linked hydroxylterminated polybutadiene. [5] Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. Dig a hole in the ground in which to place the explosive and tamp the charge with any material available to increase its effectiveness. of Tritonal on the MK 84. Senator Ben Cardin Releases Report Detailing Two Decades of Putin's Attacks on Democracy, Calling for Policy Changes to Counter Kremlin Threat Ahead of 2018, 2020 Elections | U.S. For scientific reasons we divide the explosive materials into the following: 1. H-6 is a binary explosive that is a mixture of RDX, TNT, powered aluminum, and D-2 wax with calcium chloride added. Three are conducted on a solid marble base, and one is conducted on the demonstrator's hand; each is initiated by a glowing wooden stick. In FY99, conduct static warhead test using the polynitrocubane explosive to show increase in energy performance by up to 25 percent and with comparable sensitivity to LX-14. The ideal high-energy explosive must balance different requirements. straight dynamite. Extra dynamite Both series are of lower velocity and density than high-density extra dynamite. Saving in costs realized by However, ingesting small amounts of C-4 is not known to cause any long-term impairment. Composition A-3 is not melted or cast. Too brittle a PBX can sustain damage in normal handling and succumb to extreme temperature swings or thermal shocks, while too soft a PBX may be susceptible to creep and may lack dimensional stability or strength. [48] At the end of 1944, the Holston plant and the Wabash River Ordnance Works, which used the Woolwich process, were producing 25,000 short tons (23,000t) (50 million pounds) of Composition B per month. TORPEX is an explosive based on trinitrotoluene (TNT) that gave a greater blast than TNT, but was more sensitive. [9] The rest of the ammonia was reacted with formaldehyde to produce hexamine. The mixture will become rose colored upon addition of a small quantity of ethyl alcohol. InChI=1S/C3H6N6O6/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15/h1-3H2, InChI=1/C3H6N6O6/c10-7(11)4-9-5(8(12)13)3-6(2-4)9(14)15/h1-3H2, C1N(CN(CN1[N+](=O)[O-])[N+](=O)[O-])[N+](=O)[O-], Except where otherwise noted, data are given for materials in their, UK, US, and Canadian production and development. RDX is often used in mixtures with other explosives and plasticizers or phlegmatizers (desensitizers); it is the explosive agent in C-4 plastic explosive and a key ingredient in Semtex. qualities, and is unsuitable for use underground or in poorly ventilated spaces. It is generally lower in detonation velocity, less dense, better in fume qualities, and considerably less sensitive to shock and friction than straight dynamite. The choice of binder affects hardness, safety, and stability. Straight gelatin has been used in very hard rock or as a bottom C3 During Operation Snake Eater, EVA stole C3 from the fortress of Groznyj Grad, Tselinoyarsk, when she posed as an undercover KGB operative and captive/lover of Colonel Volgin. Composition C-4 is recommended in al-Qaedas traditional curriculum of explosives training. Czech reporting suggested that the British authorities intend to run experiments on the explosive that is often used by Irish Republican Army terrorists-including the October 1993 destruction of a building in Belfast. Composition C-3 was very similar to Composition C-1, but removed the solvent and varied the exact proportions of plasticisers to improve high temperature storage. Its high sensitivity is advantageous in ditching where sympathetic detonation eliminates the need for caps or detonating fuse with individual charges. This material consisted of 88.3% RDX and a mineral oil-based plasticiser and phlegmatiser. [2] While Composition C-3 had a much wider serviceable temperature range than Composition C, it could not be stored at elevated temperatures. [24] A variety of methods for explosive residue analysis may be used to identify C-4. Blasting gelatine was tried in guns, but burst them, so Nobel set himself to discover an explosive less violent, yet equally clear and smokeless. The insensitivity is attributed to using a large amount of binder in its composition. In FY98, scale up the polynitrocubane explosive to pilot plant quantity and initiate formulation study for anti-armor warhead (Shaped Charge or explosively Formed Penetrator) loading. Further conjecture into nitro cubane chemistry has hypothesized at the possibility of polynitrocubane molecules which could achieve even greater densities. Wrappers sprayed with paraffin give fair to poor water resistance and fair fume rating, whereas a paraffin-impregnated wrapper All Navy warhead filling activities in the TNT Plant ceased in early The major longer range improvements resulting were the Navy's development of HBX type explosives together with asphaltic, "hot melt" liners for bombs and other munitions. It is crystalline and yellow or brownish, moisture-absorbing, insensitive to friction, but may be detonated by severe impact. Ammonia gelatin is comparable to a straight gelatin in the same way that a high-density ammonia dynamite is comparable to a straight dynamite, and was developed as a cheaper substitute. In particular, in the 1940s the format "Composition " was used for various compositions of the (relatively) novel explosive RDX, such as Composition B and other variants. It has beat out the theoretically more powerful octanitrocubane (ONC) in actual tests recently performed. Each Priming assembly consists of a five-foot length of detonating cord assembled with two detonating cord clips and capped at each end with a booster. Tetrytol is a mixture of ~70% tetryl (2,4,6-trinitrophenyl-methylnitramine) and ~30% TNT (2,4,6-trinitrotoluene. These names represented the identities of the developers of the various chemical routes to RDX. [7] The term RDX appeared in the United States in 1946. The main disadvantages of this material are low water resistance and problems related to non-ideal detonation, which can be a potential hazard when using ANFO. However, quantities of Composition C-1 and Composition C-2 may be found in the field. The overall reaction is:[22], Modern syntheses employ hexahydro triacyl triazine as it avoids formation of HMX. At that time (1941), the UK had the capacity to produce 70 long tons (71t) (160,000lb) of RDX per week; both Canada, an allied country and self-governing dominion within the British Empire, and the US were looked upon to supply ammunition and explosives, including RDX. Amatol 50/50 has approximately the same rate of detonation and brisance as TNT. [16], Military grade C-4 is commonly packaged as the M112 demolition block. [73] A case has been reported of a human child hospitalized in status epilepticus following the ingestion of 84.82mg/kg dose of RDX (or 1.23 g for the patient's body weight of 14.5kg) in the "plastic explosive" form. A two-component explosive of the simplest type igdanite is known, containing 94.5% of granular ammonium nitrate and 5.5% of liquid fuel, for example, diesel fuel or solar oil. Extremely high water pressures may cause a misfire. However, positive results are highly variable and the mass of RDX can range between 1.7 and 130ng, each analysis must be individually handled using magnifying equipment. Variants have different proportions and plasticisers and include composition C-2, composition C-3, and composition C-4. [3] The original RDX-based material was developed by the British during World War II and redeveloped as Composition C when introduced to the U.S. military. [9], Inserting a blasting cap into a block of C-4 to ready it for detonation. It is white, odorless and tasteless, widely used as an explosive. An explosive is a chemical material that is capable of extremely rapid combustion resulting inan explosion or detonation. The PE8 consists of 86.5% RDX, 1.0% DMDNB taggant and 12.5% of a binder composed of di(2-ethylhexyl) sebacate thickened with high molecular mass polyisobutylene. [12] Composition B: Castable mixtures of 59.5% RDX and 39.4% TNT with 1% wax as desensitizer. It is a yellow, putty-like material. Learn how and when to remove this template message, Office of Scientific Research and Development, assassination of Lebanese Prime Minister Rafic Hariri, United States Environmental Protection Agency, National Institute for Occupational Safety and Health, "Distribution and Fate of Military Explosives and Propellants in Soil: A Review", "Differentiation of Composition C4 Based on the Analysis of the Process Oil", "Demolition of the Lake Champlain Bridge", New York State Department of Transportation, History of the Second World War: United Kingdom Civil Series, "Jaipur blasts: RDX used, HuJI suspected", "Moscow Metro bombing masterminds 'will be destroyed', "Debate on Cause of Moscow Blast Heats Up", "U.S. The formulation is composed of HMX, aluminum, binder, and plasticizer. The bomb featured a 550 pound tritonal high-explosive blast warhead and was always mated with a laser guidance kit to form a laser-guided bomb. ), Composition C-3 consists of 77%85% cyclonite (RDX) and 15%23% gel made out of liquid nitro compounds (e.g. Desensitizing agents are added. Dynamite was originally a mixture of nitroglycerin and diato-mite, a porous, inert silica. Composition B, colloquially Comp B, is an explosive consisting of castable mixtures of RDX and TNT. [8] The detonation proceeds at an explosive velocity of 8,092m/s (26,550ft/s). The original material was developed by the British during World War II, and was used in the Gammon bomb. [25], RDX has a high birefringence, and the other components commonly found in C-4 are generally isotropic; this makes it possible for forensic science teams to detect trace residue on fingertips of individuals who may have recently been in contact with the compound. The gas exerts pressure in the form of a shock wave, which demolishes the target by cutting, breaching, or cratering. German DM41 fragmentation hand grenade labelled to indicate a filling of Composition B. M107 projectiles. The final material is a solid with a dirty white to light brown color, a putty-like texture similar to modeling clay, and a distinct smell of motor oil. It is well suited for use in structural excavation blasting in certain rock types. Instead of "process oil", low-viscosity motor oil is used in the manufacture of C-4 for civilian use.[6]. Wrapping on packaged C-4 indicate that it has been tagged for easier detection. nitrocellulose, an antacid, sodium nitrate, carbonaceous fuel, and sometimes sulfur. Once cured, the material cannot be easily restored to a liquid state. Grenade Assembly consists of PBXN-5 explosive booster pellet, PBXN-9 explosive pellets, grenade tube, unisex grenade shells, and ring clamp. Adding powdered aluminum as a sensitizer to slurries greatly increases the heat of explosion or the energy release. TNT. The results of 100C heat test are: 0.13% loss in the first 48 hours, no loss in the second 48 hours, and no explosions in 100 hours. An antacid is added for stability in storage. However, the use of demolitions will be restricted when under enemy observation. [76][77][78] Further research is ongoing, however, and this classification may be revised by the United States Environmental Protection Agency (EPA). SEMTEX is a plastic explosive that is odorless. Slurries, sometimes called water gels, contain ammonium nitrate partly in aqueous solution. Comp B explosives are made from TNT, RDX, and wax, such as 59.5 percent RDX, 39.5 percent TNT and 1 percent wax. The mixture is what we know to-day as dynamite; and in spite of the fact that modern chemistry has produced very many new explosives, some of terrific power, dynamite remains the safest and most widely used of all explosives. dynamite Research on a replacement for C-2 was begun prior to 1950, but the new material, new generation of Composition C (number four, C-4), did not begin pilot production until 1956. [36], In the United Kingdom (UK), RDX was manufactured from 1933 by the research department in a pilot plant at the Royal Arsenal in Woolwich, London, a larger pilot plant being built at the RGPF Waltham Abbey just outside London in 1939. The use of straight dynamite has declined because of high cost, sensitivity to shock and friction, and high flammability. [57], Traces of RDX were found on pieces of wreckage from 1999 Russian apartment bombings[58][59] and 2004 Russian aircraft bombings. 1. can be used effectively where the rock is not extremely hard and water conditions are not severe. Due to it sensitivity to bullet impact, the first weapons loaded were ones for which there would be the least possibility of rifle bullet and fragment attack, namely, submarine delivered mines and torpedoes. The M21 AT mine is 230 millimeters in diameter and 206 millimeters high. }, Page last modified: and 5.3% 2-ethylhexyl sebacate. [6], U.S. soldiers during the Vietnam War era would sometimes use small amounts of C-4 as a fuel for heating rations, as it will burn unless detonated with a primary explosive. The cross polarized light images obtained from microscopic analysis of the fingerprint are analyzed with gray-scale thresholding[26] to improve contrast for the particles. Boosters placed at regular intervals may improve fragmentation. Tools 0:38 Demonstration of the explosive properties of three different explosives; four explosions are demonstrated. [4] [citation needed] M65 bombs from 1953 containing degraded . Inserting blasting caps into blocks of C-4 explosive (bottom) being used to destroy unexploded artillery components (cylinders), A demolition charge being assembled from multiple sticks of C-4, Blocks of C-4 cut to size during a demo training session, showing the white plastic explosive material, "Differentiation of Composition C4 Based on the Analysis of the Process Oil", "Recent Developments in Composition C-4: Towards an Alternate Binder and Reduced Sensitivity", "Grosse Point Blank Microwave C4 Mercury Switch", "Steel cutting with high-explosive charges", "Thresholding in Imaging Particle Analysis (A four part series)", "Automated Mapping of Explosives Particles in Composition C-4 Fingerprints", "Bomb type and tactics point to al-Qaida", "Attorney General, on Khobar Towers Indictment", Ch. It incorporated some features based on data obtained from the United States (US). The composition is made of 95% HMX and 5% fluoroelastomers. This explosive is one of the new plastic-bonded explosives. Low-density ammonia dynamite has a weight strength of approximately 65 percent and a cartridge strength from 20 to 50 percent. [73], During the Vietnam War, at least 40 American soldiers were hospitalized with composition C-4 (which is 91% RDX) intoxication from December 1968 to December 1969. Research on a replacement for C-3 was begun prior to 1950, but the new material, C-4, did not begin pilot production until 1956. Cyclotol, which is a mixture of RDX and TNT, is an explosive used in shaped charge bombs. It is suitable for underground work because of its good fume rating. The US produced about 15,000 long tons (15,000t) per month during WWII and Germany about 7,100 tonnes (7,000 long tons) per month. The changes were made in an effort to obtain a plastic, puttylike composition to meet the requirements of an ideal explosive for molded and shaped charges that will maintain its plasticity over a wide range of temperatures and not exude oil. H-6 is an Australian produced explosive composition. Compositior C-3 is one of the Composition C series that has now been replaced by C-4, especially for loading shaped charges. This explosive is made by impregnating with liquid fuel granules of ammonium nitrate [1] One of the main disadvantages of igdanite is the high probability of failures in . During the development of a series of melt-castable explosive formulations devoid of TNT, non-TNT formulations yielded self-heating temperatures significantly lower than predicted. The Czech Republic recently announced that exports were beginning to selected countries. . It comes in the form of white or colorless granules without visible impurities or signs of moisture. gun powder 2. [71], The substance's toxicity has been studied for many years. Early implosion atomic bombs, like the Gadget exploded at Trinity in 1945, the Soviet's Joe 1 in 1949, or India in 1972, used an Composition-B [RDX-TNT mixture] as the fast explosive, with baratol used as the slow explosive. The ship was blown to bits and her crew killed, and the disaster caused so great a sensation that the manufacture of nitroglycerine was prohibited in Sweden, Belgium, and in England. Additionally, researchers observed that the reaction of Composition B-3 (IRDX/TNT) was more violent than either neat TNT or neat IRDX. A series of shots were fired at vials containing C-4 in a test referred to as "the rifle bullet test". How is Composition 3 (explosive) abbreviated? The JASSM contains the WDU-42/B (J-1000), a 1000-pound class, penetrating warhead with 240 pounds of AFX-757. The great chemist Alfred Nobel tried to improve it by mixing it with gunpowder, but the powder did not absorb all the nitroglycerine, and accidents of the most terrible kind became more and more frequent. [75], The substance has low to moderate toxicity with a possible human carcinogen classification.

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