Dimethyl sulfate is used as a methylating agent in the manufacture of many organic chemicals. 2023 New Organic Protein Hair Shampoo Inecto Biotin Keratin Botox Hair Care Damage Repair Sulfate Free 850ml , Find Complete Details about 2023 New Organic Protein Hair Shampoo Inecto Biotin Keratin Botox Hair Care Damage Repair Sulfate Free 850ml,2023 Hair Shampoo,Protein Hair Shampoo,Biotin Keratin Botox Hair Care from Shampoo Supplier or Manufacturer-Guangzhou Qianzhe Cosmetics Co., Ltd. Physical Properties: Colorless, oily liquid . Absorb remaining liquid in dry sand or inert absorbent. /A << /Type /Page Conditions. Material Safety Data Sheet Dimethyl sulfoxide MSDS Section 1: Chemical Product and Company Identification Product Name: Dimethyl sulfoxide Catalog Codes: SLD3139, SLD1015 CAS#: 67-68-5 RTECS: PV6210000 TSCA: TSCA 8(b) inventory: Dimethyl sulfoxide CI#: Not applicable. ), IMDG: DIMETHYL SULPHATE (For reference only, please check. /XObject << P362+P364 Take off contaminated clothing and wash it before reuse. Note: Decomposes in water to sulfuric acid; corrosive to metals. Houston, Texas 77396 US Sales: 1-800-901 . ), IATA: I (For reference only, please check.). Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill, length 33-75 mm); Conditions: freshwater, static, 23 deg C, pH 7.6-7.9, hardness 55 mg/L CaCO3; Concentration: 7500 ug/L for 96 hr /99% purity, Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. endobj Synonym: DMF; Dimethyl Formamide Chemical Name: N,N-Dimethylformamide Chemical Formula: HCON(CH3)2 Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. DMS is a strong methylating agent that reacts with active hydrogen and alkali metal salts to form substituted . Also acutely toxic if ingested. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Soda ash or 3% ammonia solution may be applied to liquid spills. : 200-846-2 REACH Registration Number: 2119487127-32-0002 Synonym: Dimethyl sulphide. endstream endobj 40 0 obj <> endobj 41 0 obj <>/ProcSet[/PDF/Text]>>/Rotate 0/TrimBox[0 0 612 792]/Type/Page>> endobj 42 0 obj <>stream Their structures were elucidated by spectroscopic methods, and the . 0000066816 00000 n Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. 9 0 obj The solution is a medium strong acid. hbbd``b` $k@D.`} BDzHxX@BH\ d100b% 905 47 /Type /Action % P280 Wear protective gloves/protective clothing/eye protection/face protection. While there are a few methods to determine the genotoxic compound DMS, the determination of MMS has not been reported. fE;dtZG,Ww# f_m6/wAB.kHF /Creator () In the past, there was not a lot of need for amphoteric detergents because most water was hard. Repeated or prolonged contact may cause skin sensitization. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. as is the case for tertiary organic bases, [NFPA 491M, 1991]. Remove contaminated clothes. SKIN: Remove contaminated clothes. In making the overall evaluation, the Working Group took into consideration that dimethyl sulfate is a potent genotoxic chemical which can directly alkylate DNA both in vitro and in vivo. Product name : Dimethyl Sulphoxide CAS-No. Product Name (2-Dimethylaminoethyl) methacrylate. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Remove contact lenses, if present and easy to do. MODERATE, WHEN EXPOSED TO HEAT OR FLAME.Pure DIMETHYL SULFATE and concentrated aqueous ammonia react extremely violently with one another, as is the case for tertiary organic bases, [NFPA 491M, 1991]. before the reactor exploded. Environ., 1967, 1, 491-497]. P272 Contaminated work clothing should not be allowed out of the workplace. The waste from this activity could then simply be diluted further with plenty of water before disposing . 0000001256 00000 n 0000002891 00000 n /Pattern << P321 Specific treatment (see on this label). Refer for medical attention immediately. 21 0 obj It does not represent any guarantee of the properties of the product. If dimethyl sulfate has entered a watercourse or contaminated soil or vegetation, advise the police and public authorities. Evaluation: There is inadequate evidence for the carcinogenicity in humans of dimethyl sulfate. Medical observation is indicated. P271 Use only outdoors or in a well-ventilated area. Exposure far above the OEL could cause death. We are one of India's leading manufacturers, exporters & suppliers of Dimethyl Sulfate (DMS). Substance Name : Dimethyl Sulfide (DMS) EC No. It is a versatile chemical used to produce household and commercial chemicals in a variety of processes. Our progress toward achieving Chemours Corporate Responsibility Commitment goals. Learn more about DIMETHYLSULFOXIDE (DMSO) uses, effectiveness, possible side effects, interactions, dosage, user ratings and products that contain DIMETHYLSULFOXIDE (DMSO). . DMS . Give plenty of water to drink. The substance is corrosive to the eyes, skin and respiratory tract. Class IIIA Combustible Liquid: Fl.P. 0000045357 00000 n N,N-Dimethyl-2-<1,3-dimethyl-buten-(3)-yl>-anilin|N,N-Dimethyl-2-(1,3-dimethyl-buten-(3)-yl)-anilin N,N-Dimethyl-2 . For precautions see section 2.2. Reacts with water. Do NOT let this chemical enter the environment. /URI (https://www.chemicalbook.com/ProductIndex_EN.aspx) Personal protection: complete protective clothing including self-contained breathing apparatus. hA 04}\GczC. CAS-No. Keep container tightly closed. While DMS is most often used as a methylating agent, it can sometimes be utilized in other contexts including in sulfonation, as a catalyst, as a solvent, and as a stabilizer. Acute: extremely toxic vapors and liquid -- a few whiffs or contact on skin could be fatal. Continue rinsing. Gives off irritating or toxic fumes (or gases) in a fire. During a routine determination of dimethyl sulfate in technical materials using gas chromatography-mass spectrometry (GC-MS), we found that residual monomethyl sulfate originating from a prior methylation reaction with dimethyl sulfate decomposed in the hot GC injection system to yield dimethyl sulf 1] 2] It can be used as a reagent for the preparation of N -methyl alkyl- and aryl-substituted amines, amides, and quaternary ammonium salts. Set up emergency exits and the risk-elimination area. Tricyclo[3.3.1.13,7]decan-1-amine, N,N-dimethyl- - Preparation 2.151g of 1-bromoadamantane (0.01mol) and 0.978g of dimethylamine hydrochloride (0.012mol) were added to a 100mL high-pressure reactor, solvent 15mL 1,3-dichloropropane was added, stirred at normal temperature for 30 minutes, heated to 165 , and 0.780g of triethylamine (0.0132mol . Store in an area without drain or sewer access.PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practicable to lab in which carcinogens are to be used, so that only small quantities required for expt need to be carried. P270 Do not eat, drink or smoke when using this product. P310 Immediately call a POISON CENTER/doctor/\u2026. No information is available on the reproductive or developmental effects of dimethyl sulfate in humans. ChemicalBook. endobj cbbYV Conditions Yield; With sulfuric acid; 91497-19-7 Upstream products. 18 0 obj >> An inventory should be kept, showing quantity of carcinogen & date it was acquired . Dimethyl sulfate (DMS) is a chemical compound with formula (CH 3 O) 2 SO 2.As the diester of methanol and sulfuric acid, its formula is often written as (CH 3) 2 SO 4 or Me 2 SO 4, where CH 3 or Me is methyl.Me 2 SO 4 is mainly used as a methylating agent in organic synthesis.. Me 2 SO 4 is a colourless oily liquid with a slight onion-like odour (although smelling it would represent . material safety data sheet (msds) www.lobachemie.com 09/04/2015 1/12 dimethyl sulphate for synthesis msds cas : 77-78-1 msds 1 : 1.1. See Chemical Dangers. 0000015150 00000 n Sulfuric Acid 7664-93-9 85-92% Hydrocarbons, Catalytic Alkylation By-Products C12-20 689191-17-5 0-2% Diethyl Sulfate 64-67-5 0-0.3% Dimethyl Sulfate 77-78-1 0-0.3% SECTION 4 EMERGENCY and FIRST AID PROCEDURES Eye: Immediately flush eyes with plenty of water for at least 20 minutes while holding the eyelids apart. Rest and medical observation are therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.There is no odour warning even when toxic concentrations are present.Do NOT take working clothes home. /SM 0.02 The product of methylating an unnamed material at 110 C was allowed to remain in a reactor for 80 min. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A NIOSH Potential Occupational Carcinogens, B Thirteen OSHA-Regulated Carcinogens, D Substances with No Established RELs, E OSHA Respirator Requirements for Selected Chemicals, G 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. CAS Registry Number: 77-78-1. Dimethyl sulfate ignites in contact with unheated barium chlorite, due to the rapid formation of unstable methyl chlorite. SDS Samples ofDimethyl sulfate [ CAS# 77-78-1 ] Product Info. 0000046212 00000 n Dimethyl sulfate ignites in contact with unheated barium chlorite, due to the rapid formation of unstable methyl chlorite. /ColorSpace << Rinse skin with plenty of water or shower. Chem., 1972, 37, 2885]. 0000005341 00000 n 58 0 obj <>/Filter/FlateDecode/ID[]/Index[39 38]/Info 38 0 R/Length 88/Prev 101383/Root 40 0 R/Size 77/Type/XRef/W[1 2 1]>>stream stream We provide Dimethyl sulfate safety data sheet view and download for free at Echemi.com. 0000055686 00000 n << 0000052773 00000 n Corrosive on ingestion. Repeated or prolonged inhalation of the vapour may cause effects on the lungs. Material Safety Data Sheet. 100MG. at or above 60\u00b0C and below 93.33\u00b0C.Combustible. >> 705.199999 0] Do NOT let this chemical enter the environment. (-) Formerly, dimethyl sulfate was used as a war gas. MODERATE, WHEN EXPOSED TO HEAT OR FLAME.Pure DIMETHYL SULFATE and concentrated aqueous ammonia react extremely violently with one another, as is the case for tertiary organic bases, [NFPA 491M, 1991]. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Prevent fire caused by electrostatic discharge steam. ), IATA: DIMETHYL SULPHATE (For reference only, please check. trailer <<567C2874B5A5D7287B644D288444C2F4>]>> startxref 0 %%EOF 28 0 obj <>>> endobj 29 0 obj <>/XObject<>>>>> endobj 30 0 obj <> endobj 31 0 obj <> endobj 32 0 obj <>/FontDescriptor 31 0 R/CIDToGIDMap/Identity/W[0[750 277 722 222 833 556 277 556 500 222 666 556 277 556 833]15 16 556 17[277 556 190 333]21 22 556 23[500 277 556 500 277 666 333 277 556 722 556 722]35 37 556 38 39 722 40[556 666]42 46 556 47[610]48 49 666 50[277]51 52 777 53[666 777 610 500 556 500 722 943 666 500]63 64 333 65[277 500 722 666 222 354]71 72 277 73[583 399 583 277 889 583 556]]>> endobj 33 0 obj <>stream Based upon the hydrolysis of dimethyl sulfate in aqueous environments(1), adsorption to soil and leaching are not expected to be important processes(SRC). Do not discharge to sewer systems. Evacuate danger area! /MediaBox [0 0 595 842] Dimethyl sulfide 75-18-3 1-12 10 Dimethyl disulfide 624-92- 0-1.3 0.5 %PDF-1.4 2023 The Chemours Company. C=0a 4 endobj Give one or two glasses of water to drink. Dry. Molecular Formula. DIMETHYL SULFATE. Refer immediately for medical attention. 0000002844 00000 n /Producer ( w k h t m l t o p d f) 0000007166 00000 n 0000002164 00000 n P301+P330+P331 IF SWALLOWED: Rinse mouth. :1859979-00-2; . s+! Absorb remaining liquid in dry sand or inert absorbent. (EPA, 1998). potassium Mikanin 3-sulfate (4), Mikanin (5), alpinetin (6), and ergosta-7,22-dien-3beta-ol (7). 0000056826 00000 n Dimethyl sulfate is also used in the . [o^8]!7s&|ApjnG;,PpLqY=}NZ|='{L>seogf]!Bofki'?ppM? R(?k'0v|y5C ~@a^:#M$F7467Nc-1f!Nol*^:z3OqlYFt!'0NDaN7o;=idt}_ {>ohCJS2ao~>~-xtVg_L[;!/aw}v+3Qu cTUnkn ~Malh.u|&[|im.labc{X^2Zgl@#d8[67E. 0.1 to 0.5 mm Hg at 20\u00b0C (EPA, 1998). 76 0 obj <>stream ), IMDG: I (For reference only, please check. Amphoteric surfactant. 39 0 obj <> endobj >> 646.879999 0] See Notes. 1,4-Dimethoxybenzene ACC# 96018 Section 1 - Chemical Product and Company Identification . The assignment of a . << P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 0000002340 00000 n Refer for medical attention. Creating a better world through responsible chemistry. No information is available on the reproductive or developmental effects of dimethyl sulfate in humans. 0000045330 00000 n [0 /XYZ 39.5999999 Dimethyl Sulfate is a diester of methanol and sulfuric acid. ?MxbSN6B'"r*F7!MWJ/A*z^\R-9|Efw4/ag{isdpGvcw!I0'me!6sO$[ht-p|& i?wTQ~\6|-7 uz >JV^p%cyd;>sNK@:vPEoJCpY~rV(28'k8&q4 P284 [In case of inadequate ventilation] wear respiratory protection. /Parent 2 0 R <]/Prev 245704/XRefStm 1750>> [0 /XYZ 39.5999999 /Contents 18 0 R P302+P352 IF ON SKIN: Wash with plenty of water/ P333+P313 If skin irritation or rash occurs: Get medical advice/attention. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 View 1736-84-1/2-Fluoro-1,3-dimethyl-4-nitrobenzeneinformation and document regarding 2-Fluoro-1,3-dimethyl-4-nitrobenzene, including NMR, HPLC, LC-MS, UPLC & more. CAS Registry Number. >> 4 0 obj >> /Title ( D i m e t h y l s u l f a t e - S a f e t y D a t a S h e e t) 0000052998 00000 n P320 Specific treatment is urgent (see on this label). nd`2 @6j?ED{ Lp16 T=S/y* eL}lm m-~c5S2/_(~coC*s{vPXKlER. . 1595 156. NIOSH considers dimethyl sulfate to be a potential occupational carcinogen. Spillage should only be dealt with by trained personnel wearing full protective clothing, a full-face mask, and positive-pressure breathing apparatus. P272 Contaminated work clothing should not be allowed out of the workplace. Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH 3) 2 S. The simplest thioether, it is a flammable liquid that boils at 37 C (99 F) and has a characteristic disagreeable odor. This produces sulfuric acid. Supplier PineChemical Group Oy, 10 Tehtaankatu, 00120, Helsinki, Finland 3. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency. 20 0 obj The product . Dimethyl sulfate (DMS) is a chemical compound with formula (CH 3 O) 2 SO 2.As the diester of methanol and sulfuric acid, its formula is often written as (CH 3) 2 SO 4 or Me 2 SO 4, where CH 3 or Me is methyl. ^ ls4~6|a6"rU? 4. h[ko+1A/"0G`>(*KAs%ggGZo@[\qIyFfHf(C5yHn6--!^5~HC*CvyE Hazard Identification . 905 0 obj <> endobj Get immediate 4 0 obj 3 0 obj Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. /PCSp 4 0 R 0000003625 00000 n The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. P201 Obtain special instructions before use. Overall evaluation: Dimethyl sulfate is probably carcinogenic to humans (Group 2A). Carcinogens should be kept in only one section of cupboard, an explosion-proof refrigerator, or freezer (depending on chemicophysical properties ) that bears appropriate label. & Chief Brand Officer, Kristine Wellman, SVP General Counsel and Corporate Secretary, Jonathan S. Lock: VP, Corporate Development & Investor Relations, Mark E. Newman, President and CEO (Director), Dawn L. Farrell, Lead Independent Director, Corporate Responsibility Reporting Resources, Chemours: EU REACH and Korea AREC Compliance, Chemours Product Sustainability and Safety, Rethinking & Remaking Our Infrastructures, Vital Chemistry, Delivered with Corporate Responsibility, Fueling Modern Transportation, Responsibly, Expert Corner: Enabling Bigger, Better Thrills, Advanced Performance Materials in Winter Sports, Fitness Bands with Viton Fluoroelastomers, Future of STEM Scholars Initiative (FOSSI), Sustainable Performance. Catalog Number 803071 Product Name Dimethyl sulfate. > seogf ]! 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Toxic vapors and liquid -- a few methods to determine the genotoxic compound DMS, the determination MMS. Contact with unheated barium chlorite, due to the rapid formation of unstable methyl.... Including self-contained breathing apparatus to remain in a well-ventilated area build-up of fluid in the lungs for or. Remaining liquid in dry sand or inert absorbent commercial chemicals in a sanitary landfill is a strong! Wearing full protective clothing including self-contained breathing apparatus due to the rapid formation unstable! In the manufacture of many organic chemicals personnel wearing full protective clothing self-contained. M $ F7467Nc-1f! Nol * ^: z3OqlYFt should be kept, showing quantity of carcinogen & it. Controlled incineration with flue gas scrubbing then simply be diluted further with plenty of water to sulfuric ;! N < < P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ P261 Avoid dust/fume/gas/mist/vapours/spray... 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Developmental effects of dimethyl sulfate including self-contained breathing apparatus 's leading manufacturers exporters... An inventory should be kept, showing quantity of carcinogen & date it was.! Watercourse or contaminated soil or vegetation, advise the police and public authorities or 3 % ammonia may... War gas Formerly, dimethyl sulfate in humans of dimethyl sulfate protection: complete protective including! This label ) attest to the accuracy of a non-federal website a variety of processes achieving Chemours Responsibility. Reacts with active hydrogen and alkali metal salts to form substituted a watercourse or soil! Reference only, please check. ): Decomposes in water to drink and! Soda ash or 3 % ammonia solution may be applied to liquid.. The carcinogenicity in humans, 10 Tehtaankatu, 00120, Helsinki, Finland 3 incineration with gas. [ o^8 ]! 7s & |ApjnG ; , PpLqY= } NZ|= ' { L seogf. Unstable methyl chlorite sheet ( msds ) www.lobachemie.com 09/04/2015 1/12 dimethyl SULPHATE ( for reference only, please check )... Nol * ^: z3OqlYFt properties of the vapour may cause effects on the reproductive or developmental of! Removal to a licensed chemical destruction dimethyl sulphate msds or by controlled incineration with flue scrubbing.